The Economist
May 5th 2018
Science and technology 77
2
tion, a process that provides drinking wa-
ter for around 300m people. To do so, they
have made a membrane laced with micro-
scopic Turing patterns that can remove
salts from water up to four times faster
than commercial alternatives. Their re-
search is published thisweek in
Science
.
During desalination, seawater is often
pumped first through a porous “nanofiltra-
tion” membrane made of a substance
called polyamide. This removes bulky
ions, such as magnesium and sulphate, as
well as bacteria and other large particles.
After that, it passes through a secondmem-
brane which has even tinier pores. This
step, called reverse osmosis, removes ions
smaller than magnesium and sulphate,
particularly the sodium and chloride ions
that make up common salt and that give
seawater its characteristic taste.
The membranes employed for reverse
osmosis are rough, and so have a large sur-
face area through which water can pass.
Nanofiltration membranes, by contrast,
are smooth. That, Dr Zhang reasoned,
meant that they might be improved. To in-
troduce the necessary roughness he need-
ed some way to modify the chemical reac-
tion by which the membranes are made.
This process, known as interfacial poly-
merisation, involves two chemicals. One,
piperazine, is soluble in water. The other,
trimesoyl chloride (
TMC
), can be dissolved
only in an organic solvent such as decane,
an oily hydrocarbon.
When piperazine and
TMC
meet, they
react to form polyamide. But if the one is
dissolved in water and the other in oil,
which famously do not mix, then the reac-
tion can happen only at the surface where
the oil is floating on the water. The result is
a polyamide sheet. In practice, in industrial
conditions, this reaction is usually per-
formed on a porous support that is first
soaked in piperazine before one side is ex-
posed to
TMC
. The polyamide sheet then
forms on that side of the support. Dr
Zhang’s insightwas to see that this arrange-
ment might be modified to be the type of
two-chemical system that Turing de-
scribed in his paper—and that if it could be,
the resulting patterns would act as surface-
area-increasing bumps.
For a system to form Turing patterns,
two chemicals must diffuse at different
rates through the medium in which the re-
action is taking place. The rates cannot,
however, be too different. The ideal dis-
crepancy is about a factor often. To achieve
this, Dr Zhang added polyvinyl alcohol to
the piperazine solution, to make it more
viscous and slowpiperazine’s diffusion.
The upshot was the creation of polya-
mide sheets full of either tiny, hollow bub-
bles or interconnecting tubes, depending
on the concentration of polyvinyl alcohol
used. These are just the sorts of surface-
area-increasing features that Dr Zhang had
hoped for. And they did the job. The best
were able to handle a fourfold increase in
flowratewith no loss of performance.
Flushed with success, Dr Zhang is now
turning his attention to the reverse-osmo-
sis membranes. Though these are already
rough, he thinks he can make them
rougher. They, too, are made by interfacial
polymerisation, so he may well be able to
do so. And if both sorts of membrane can
be improved, the process of desalination,
which is likely to become more important
as demand for water increases, will be
made cheaper andmore effective.
7
F
OR the feeding of babies, everyone
agrees that “breast isbest”. It isnot, how-
ever, always convenient. Textileworkers in
Bangladesh, who are mostly women, are
entitled to four months’ maternity leave.
Once this is over, theyoften endupparking
their childrenwith relativeswhen they are
at work. Those with refrigerators at home
can use breast pumps to express milk be-
fore they go on shift, and leave it behind to
chill. But fridges are expensive, and many
do not own one. Unchilled milk goes off
within a couple of hours so the inevitable
outcome for fridgeless mothers and their
babies is the use of infant formula.
A chance meeting in a coffee shop in
Dhaka may, though, have helped with this
problem. It was between Sabrina Rasheed
(pictured above, right), a child-nutrition ex-
pert at the International Centre for Diar-
rhoeal Disease Research in Bangladesh,
and three Canadian students. Two, Scott
Genin and Jayesh Srivastava, are engi-
neers. The third, Micaela Langille-Collins,
is a trainee doctor. The upshot of the en-
counter was that Dr Rasheed gave the stu-
dents the job of designing a low-cost, low-
techway of keepingmothers’ milkhealthy
in Bangladesh’s tropical climate, without
resorting to refrigeration.
The device the trio came up with,
shown in the picture, is a cheap pasteurisa-
tion machine based on a food warmer of
the sort used in canteens. Instead of food,
the warmer’s vessels are filled with paraf-
finwax, which is liquefied by the heat. Bot-
tles containing expressed milk, held in
bags made of silicon-coated nylon, are
hung from a plate and bathed in the wax,
which is then heated further. A thermom-
eter in the wax registers the temperature,
and once that reaches 72.5°C—the level re-
quired for pasteurisation—a timer is start-
ed. After15 seconds this sets offan alarm to
indicate that the milk has been cooked
enough to kill hostile bacteria, and the bot-
tles are removed and allowed to cool.
Thus pasteurised, microbiological tests
show, the milk’s shelf life at local room
temperatures increases from two hours to
somewhere between six and eight. This
meansno refrigeration is requiredand rela-
tives looking after babies need collect ex-
pressed milk from the factory, where the
machine is located, only once a day. The
pasteurisedmilkalso retainsmost of its nu-
tritional value.
With the aid of ten donated breast
pumps, Ms Langille-Collins and her col-
leagues tested their invention at the Inter-
fab Shirt Manufacturing workshop, north
ofDhaka. To startwith, mothers employed
there were suspicious, says Aliya Ma-
drasha, head of human resources at the
factory. That changed, though, when they
came to understand both the convenience
of the system, and the economy of no lon-
ger having to buy formulamilk.
The newmachine is also a hit with the
factory’s management. Expressing their
milk at the beginning of a shift means
women with babies suffer less discomfort
during the day, and so aremore productive.
Absenteeism among mothers has also
dropped, from five days a month to one.
The biggest benefit, though, according to
Ahasan Kabir Khan, the factory’s owner, is
the retention of skilled staff who might
otherwise leave to nurse their children.
Mr Khan is so impressed that he now
wants toput pasteurisationmachines inall
his factories. Other factoryowners, too, are
asking for the machines. Dr Rasheed and
Ms Langille-Collins are therefore develop-
ing a commercial version of the machine,
in collaboration with 10xBeta, a firm in
New York. If their patent application is ap-
proved, they plan to lease the devices to
firms all over Bangladesh and then, subse-
quently, to people in other poor countries
all around theworld.
7
Working mothers
Express delivery
Dhaka
Apasteurisationmachine forhuman
breastmilk
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